李相波,马广义,陈祥曦,马力.船用E500钢在海水中阴极极化氢脆敏感性研究[J].装备环境工程,2017,14(2):6-10. LI Xiang-bo,MA Guang-yi,CHEN Xiang-xi,MA Li.Susceptibility to Hydrogen Embrittlement of E500 Steel for Vessel in Seawater[J].Equipment Environmental Engineering,2017,14(2):6-10.
船用E500钢在海水中阴极极化氢脆敏感性研究
Susceptibility to Hydrogen Embrittlement of E500 Steel for Vessel in Seawater
投稿时间:2016-08-21  修订日期:2017-02-15
DOI:10.7643/ issn.1672-9242.2017.02.002
中文关键词:  E500钢  氢脆  阴极保护电位
英文关键词:E500 steel  hydrogen embrittlement  cathodic protection potential
基金项目:“十二五”环境试验计划项目(H082012B001)
作者单位
李相波 中国船舶重工集团公司第七二五研究所 海洋腐蚀与防护重点实验室,山东 青岛 266101 
马广义 海军驻青岛地区装备修理监修室,山东 青岛 266001 
陈祥曦 中国船舶重工集团公司第七二五研究所 海洋腐蚀与防护重点实验室,山东 青岛 266101 
马力 中国船舶重工集团公司第七二五研究所 海洋腐蚀与防护重点实验室,山东 青岛 266101 
AuthorInstitution
LI Xiang-bo State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, Qingdao 266101, China 
MA Guang-yi Navy Equipment Repair Superintend Office for Qingdao District, Qingdao 266001, China 
CHEN Xiang-xi State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, Qingdao 266101, China 
MA Li State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, Qingdao 266101, China 
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中文摘要:
      目的 研究阴极保护电位对E500钢在海水中氢脆敏感性的影响。方法 采用慢应变速率拉伸试验(SSRT),同时利用三电极体系进行不同电位极化,并结合扫描电镜进行试样断口观察。结果 随着阴极保护电位负移,E500钢在海水中的氢脆敏感性增加,阴极保护电位为-0.95 V(vs.SCE)时,拉伸试样出现脆性解理断裂特征,电位为-1.00 V时,E500钢断口呈脆性断裂特征。结论 根据氢脆系数拟合曲线得出,当氢脆系数达到25%时,E500钢最负阴极保护电位应为-0.913 V。
英文摘要:
      Objective To study influences of cathodic protection potential on susceptibility to hydrogen embrittlement (HE) of E500 steel in seawater. Methods Different polarization activities were investigated in seawater through three electrode electrochemical system under slow strain rate tests and combined with scanning electron microscopy (SEM) of fracture surfaces. Results The susceptibility to hydrogen embrittlement of E500 in seawater increased with the decrease of cathodic protection potential. The fracture surface of specimen after slow strain rate test exhibited cleavage brittle fracture at -0.95 V (vs.SCE). E500 steel was subject to HE in sea water at -1.00 V. Conclusion According to the fitting curve of hydrogen embrittlement coefficient, when hydrogen embrittlement coefficient reaches 25%, the most negative cathodic protection potential for E500 steel should be -0.913 V.
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