Performance Evolution of Quartz/Mullite Fiber Insulation Tiles under High-temperature Exhaust Gas Environment

LUAN Zhiqiang, SHANG Lei, ZHAI Hanlei, PENG Xing, TAN Mingyi, HAN Wenbo

Equipment Environmental Engineering ›› 2026, Vol. 23 ›› Issue (7) : 133-142.

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Equipment Environmental Engineering ›› 2026, Vol. 23 ›› Issue (7) : 133-142. DOI: 10.7643/issn.1672-9242.2026.07.013
Aviation and Aerospace Equipment

Performance Evolution of Quartz/Mullite Fiber Insulation Tiles under High-temperature Exhaust Gas Environment

  • LUAN Zhiqiang1, SHANG Lei2, ZHAI Hanlei2, PENG Xing3,*, TAN Mingyi1, HAN Wenbo1
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Abstract

The work aims to evaluate the performance evolution and failure mechanisms of quartz/mullite fiber insulation tiles under simulated coupled high-temperature, engine exhaust, and rain conditions, providing an experimental basis for material selection and service-life prediction of thermal protection systems in high-speed aircrafts. Quartz/mullite fiber insulation tiles of broad application prospects were subject to cyclic corrosion-fatigue tests (1-5 cycles) in simulated rain and engine exhaust atmospheres. Compression tests at room temperature and 1 100 ℃ were performed with an electronic universal testing machine. Microstructure and phase composition were analyzed by SEM and XRD; pore structure and thermal properties after several cycles were characterized by mercury intrusionporosimetry, a plate thermal conductivity meter, and a thermal dilatometer to clarify the damage behavior of insulation tiles in the environment of rain and engine exhaust. The results showed that compressive strength at room temperature decreased with increasing cycles, and fracture strain dropped from 65% to about 20%. Compressive strength at high temperature first increased and then decreased. XRD indicated that quartz gradually transformed from silicate to α-quartz and cristobalite; a distinct phase change accompanied by micro-cracking occurred after 4 cycles. SEM showed fiber fragmentation and increased porosity. Thermal conductivity decreased after 3 cycles but remained at a low level throughout. Under the simulated environment, the insulation tiles experience progressive mechanical degradation due to phase transformation and fiber-skeleton deterioration, while still retaining excellent thermal insulation performance. The findings provide a reference for service assessment of thermal protection materials in high-speed aircrafts.

Key words

quartz/mullite fiber insulation tile / multi-field coupled environment / fatigue test / thermal insulation performance / mechanical properties

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LUAN Zhiqiang, SHANG Lei, ZHAI Hanlei, PENG Xing, TAN Mingyi, HAN Wenbo. Performance Evolution of Quartz/Mullite Fiber Insulation Tiles under High-temperature Exhaust Gas Environment[J]. Equipment Environmental Engineering. 2026, 23(7): 133-142 https://doi.org/10.7643/issn.1672-9242.2026.07.013

References

[1] DENG Y, HAO Y, WANG H F, et al.Effect of Temperature and Atmosphere on the Fracture Toughness and Failure Mechanisms of Two-Dimensional Plain-Woven SiCf/SiC Composites: Experiments and Modeling[J]. Acta Mechanica Sinica, 2025, 41(12): 124333.
[2] WHITE D M, WICKLEIN M, CLEGG R A, et al.Multi-Layer Insulation Material Models Suitable for Hypervelocity Impact Simulations[J]. International Journal of Impact Engineering, 2008, 35(12): 1853-1860.
[3] UYANNA O, NAJAFI H.Thermal Protection Systems for Space Vehicles: A Review on Technology Development, Current Challenges and Future Prospects[J]. Acta Astronautica, 2020, 176: 341-356.
[4] CHANG X Y, CHENG X T, ZHANG H, et al.Superelastic Carbon Aerogels: An Emerging Material for Advanced Thermal Protection in Extreme Environments[J]. Advanced Functional Materials, 2023, 33(26): 2215168.
[5] WANG M C, LI L Y, LI Z Y, et al.Mullite Whiskers Grown in Situ Reinforce a Pre-Ceramic Resin Adhesive for Silicon Carbide Ceramics[J]. Ceramics International, 2019, 45(8): 11131-11135.
[6] ZHANG R Y, LI J J, WANG Z Q, et al.Preparation of Porous Mullite Ceramics Composed Entirely of Overlapping and Interlocking Mullite Whiskers through Whisker in-Situ Growth[J]. Journal of Advanced Ceramics, 2025, 14(4): 9221055.
[7] LAO D, LIN P, LIU X J, et al.A Novel Approach to Prepare High Strength and High Porosity Reticulated Porous Ceramics by In-Situ Synthesis of Mullite Whiskers[J]. Ceramics International, 2021, 47(10): 14561-14568.
[8] DEVAPAL D, GOPAKUMAR M P, PRABHAKARAN P V, et al.Ceramic Coating on Flexible External Insulation Blankets for Reusable Missions[J]. Current Science, 2018, 114(1): 137-143.
[9] TAO X, ZHANG L Y, MA X H, et al.Preparation of a Flexible High Emissivity Coating on Quartz Fiber Fabric for Thermal Protection[J]. Ceramics International, 2017, 43(16): 14292-14300.
[10] REINDERS L, PFEIFER S, KRÖNER S, et al. Development of Mullite Fibers and Novel Zirconia-Toughened Mullite Fibers for High Temperature Applications[J]. Journal of the European Ceramic Society, 2021, 41(6): 3570-3580.
[11] ZHANG X, ZHANG T, YI Z H, et al.Multiscale Mullite Fiber/Whisker Reinforced Silica Aerogel Nanocomposites with Enhanced Compressive Strength and Thermal Insulation Performance[J]. Ceramics International, 2020, 46(18): 28561-28568.
[12] ZHANG Y, WU Y J, YANG X K, et al.High-Strength Thermal Insulating Mullite Nanofibrous Porous Ceramics[J]. Journal of the European Ceramic Society, 2020, 40(5): 2090-2096.
[13] ZHANG X Y, HOU F, DU H Y, et al.Preparation of Ceramic Fiber Threads with Enhanced Abrasion Resistance Performance[J]. Materials, 2024, 17(3): 599.
[14] LI X X, YAN L W, ZHANG Y B, et al.Lightweight Porous Silica Ceramics with Ultra-Low Thermal Conductivity and Enhanced Compressive Strength[J]. Ceramics International, 2022, 48(7): 9788-9796.
[15] ESHARGHAWI A, PENOT C, NARDOU F.Contribution to Porous Mullite Synthesis from Clays by Adding Al and Mg Powders[J]. Journal of the European Ceramic Society, 2009, 29(1): 31-38.
[16] SAHRAOUI T, BELHOUCHET H, HERAIZ M, et al.The Effects of Mechanical Activation on the Sintering of Mullite Produced from Kaolin and Aluminum Powder[J]. Ceramics International, 2016, 42(10): 12185-12193.
[17] LIU R P, XIANG D P.Low-Temperature Synthesis of Mullite by Molten Molybdenum Trioxide Assisted Mesoporous Aluminum Source Dissolution[J]. Ceramics International, 2023, 49(16): 27688-27696.
[18] NASERI M, OMIDKHAH M R.Optimizing the Fabrication Conditions of Monolithic Mullite Whisker Membrane from Kaolin and Bauxite Using the Taguchi Method[J]. Ceramics International, 2023, 49(14): 23612-23626.
[19] DENG X G, RAN S L, HAN L, et al.Foam-Gelcasting Preparation of High-Strength Self-Reinforced Porous Mullite Ceramics[J]. Journal of the European Ceramic Society, 2017, 37(13): 4059-4066.
[20] LIU J X, WAN Y G, XIAO B, et al.The Preparation and Performance Analysis of Zirconium-Modified Aluminum Phosphate-Based High-Temperature (RT-1500 ℃) Resistant Adhesive for Joining Alumina in Extreme Environment[J]. Journal of Advanced Ceramics, 2024, 13(7): 911-932.
[21] DONG X, SUI G F, YUN Z Q, et al.Effect of Temperature on the Mechanical Behavior of Mullite Fibrous Ceramics with a 3D Skeleton Structure Prepared by Molding Method[J]. Materials & Design, 2016, 90: 942-948.
[22] QIN Z, XU X J, XU T F, et al.High-Strength Thermal Insulating Porous Mullite Fiber-Based Ceramics[J]. Journal of the European Ceramic Society, 2022, 42(15): 7209-7218.
[23] INFED F, HANDRICK K, LANGE H, et al.Development of Thermal Protective Seal for Hot Structure Control Surface Actuator Rod[J]. Acta Astronautica, 2012, 70: 122-138.
[24] SHEN S B, ZHAO Y N, DU H Y, et al.Mullite Fiber Sealing Pad with Favorable High-Temperature Rebound Resilience Fabricated through Colloidal Processing[J]. Ceramics International, 2014, 40(6): 8905-8909.
[25] HAMZA M H, SCHICHTEL J J, CHATTOPADHYAY A.Multiphysics Model of Thermomechanical Oxidative Degradation in SiC/SiC Ceramic Matrix Composite Microstructures[J]. Journal of the European Ceramic Society, 2025, 45(10): 117335.
[26] ALMEIDA R S M, TUSHTEV K, CLAUß B, et al. Tensile and Creep Performance of a Novel Mullite Fiber at High Temperatures[J]. Composites Part A: Applied Science and Manufacturing, 2015, 76: 37-43.
[27] ZHANG X, ZHANG X Y, WANG Z Y, et al.Preparation and Properties of Elastic Mullite Fibrous Porous Materials with Excellent High-Temperature Resistance and Thermal Stability[J]. Materials, 2024, 17(13): 3235.
[28] POERSCHKE D L, ROSSOL M N, ZOK F W.Intermediate Temperature Oxidative Strength Degradation of a SiC/SiNC Composite with a Polymer-Derived Matrix[J]. Journal of the American Ceramic Society, 2017, 100(4): 1606-1617.
[29] DETWILER K N, OPILA E J.Oxidation of SiC/BN/SiC Ceramic Matrix Composites in Dry and Wet Oxygen at Intermediate Temperatures[J]. Journal of the European Ceramic Society, 2022, 42(10): 4110-4120.
[30] AL NASIRI N, PATRA N, NI N, et al.Oxidation Behaviour of SiC/SiC Ceramic Matrix Composites in Air[J]. Journal of the European Ceramic Society, 2016, 36(14): 3293-3302.
[31] LEE K N, WATERS D L, PULEO B J, et al.Development of Oxide-Based High Temperature Environmental Barrier Coatings for Ceramic Matrix Composites via the Slurry Process[J]. Journal of the European Ceramic Society, 2021, 41(2): 1639-1653.
[32] LEE K N, GARG A, JENNINGS W D.Effects of the Chemistry of Coating and Substrate on the Steam Oxidation Kinetics of Environmental Barrier Coatings for Ceramic Matrix Composites[J]. Journal of the European Ceramic Society, 2021, 41(11): 5675-5685.
[33] RUGGLES-WRENN M, BOUCHER N, PRZYBYLA C.Fatigue of Three Advanced SiC/SiC Ceramic Matrix Composites at 1 200 ℃ in Air and in Steam[J]. International Journal of Applied Ceramic Technology, 2018, 15(1): 3-15.
[34] RIDLEY M, KANE K, LANCE M, et al.Steam Oxidation and Microstructural Evolution of Rare Earth Silicate Environmental Barrier Coatings[J]. Journal of the American Ceramic Society, 2023, 106(1): 613-620.
[35] MORSCHER G N, PANAKARAJUPALLY R P, HOFFMAN L.The Versatility of HVOF Burner Rig Testing for Ceramic Matrix Composite Evaluation[J]. Journal of Composites Science, 2021, 5(8): 223.
[36] KIM T T, MALL S, ZAWADA L P, et al.Simultaneous Fatigue and Combustion Exposure of a SiC/SiC Ceramic Matrix Composite[J]. Journal of Composite Materials, 2010, 44(25): 2991-3016.
[37] OKITA Y, MIZOKAMI Y, HASEGAWA J.Erosion Testing of Environmental Barrier-Coated Ceramic Matrix Composite and Its Behavior on an Aero-Engine Turbine Vane under Particle-Laden Hot Gas Stream[J]. Journal of Turbomachinery, 2020, 142(6): 061001.
[38] 中国人民解放军总装备部. 军用装备实验室环境试验方法第8部分: 淋雨试验: GJB 150.8A—2009[S]. 北京: 中国标准出版社, 2009.
General Armaments Department of the People’s Liberation Army. Laboratory Environment Test Methods for Military Material—Part 8: Rain Test: GJB 150.8A— 2009[S]. Beijing: Standards Press of China, 2009.
[39] HEANEY P J.Structure and Chemistry of the Low-Pressure Silica Polymorphs[J]. Silica: Physical Behavior, Geochemistry, and Materials Applications, 1994(29): 1-40.
[40] PALMER D C.Stuffed Derivatives of the Silica Polymorphs[J]. Silica: Physical Behavior, Geochemistry, and Materials Applications, 1994(29): 83-122.
[41] PAGLIARI L, DAPIAGGI M, PAVESE A, et al.A Kinetic Study of the Quartz-Cristobalite Phase Transition[J]. Journal of the European Ceramic Society, 2013, 33(15/16): 3403-3410.
[42] GUPTA T K, JEAN J H.Origin of Cristobalite Formation during Sintering of a Binary Mixture of Borosilicate Glass and High Silica Glass[J]. Journal of Materials Research, 1994, 9(4): 999-1005.
[43] DAPIAGGI M, PAGLIARI L, PAVESE A, et al.The Formation of Silica High Temperature Polymorphs from Quartz: Influence of Grain Size and Mineralising Agents[J]. Journal of the European Ceramic Society, 2015, 35(16): 4547-4555.
[44] LIANG J J, LIN Q H, ZHANG X, et al.Effects of Alumina on Cristobalite Crystallization and Properties of Silica-Based Ceramic Cores[J]. Journal of Materials Science & Technology, 2017, 33(2): 204-209.
[45] KAZEMI A, FAGHIHI-SANI M A, NAYYERI M J, et al. Effect of Zircon Content on Chemical and Mechanical Behavior of Silica-Based Ceramic Cores[J]. Ceramics International, 2014, 40(1): 1093-1098.
[46] KHAMKONGKAEO A, BOOTCHANONT A, KLYSUBUN W, et al.Effect of Phosphate Compound on Physical and Mechanical Properties of SiO2 Ceramic[J]. Ceramics International, 2019, 45(1): 1356-1362.
[47] YANG S W, WANG Q H, ZHANG X W, et al.Inhibiting Crystallization and Enhanced Non-Wettability Against Molten Si of Fused Silica Ceramic with Addition of Β-Si3N4[J]. Journal of Crystal Growth, 2023, 613: 127198.
[48] BRUNAUER G, FREY F, BOYSEN H, et al.High Temperature Thermal Expansion of Mullite: An in Situ Neutron Diffraction Study up to 1600 ℃[J]. Journal of the European Ceramic Society, 2001, 21(14): 2563-2567.
[49] SCHNEIDER H, FISCHER R X, SCHREUER J.Mullite: Crystal Structure and Related Properties[J]. Journal of the American Ceramic Society, 2015, 98(10): 2948-2967.
[50] MEILLE S, LOMBARDI M, CHEVALIER J, et al.Mechanical Properties of Porous Ceramics in Compression: On the Transition between Elastic, Brittle, and Cellular Behavior[J]. Journal of the European Ceramic Society, 2012, 32(15): 3959-3967.
[51] NIU S X, LIU Z P, LUO Y S, et al.Reinforcement of Silica-Based Ceramic Cores Based on Amorphous and Polycrystalline Mullite Fibers[J]. Ceramics International, 2023, 49(19): 31378-31384.
[52] ŠTUBŇA I, TRNÍK A, VOZÁR L. Thermomechanical Analysis of Quartz Porcelain in Temperature Cycles[J]. Ceramics International, 2007, 33(7): 1287-1291.
[53] TRNÍK A, ŠTUBŇA I, VARGA G, et al. Structural and Thermomechanical Properties of Stove Tile Ceramics[J]. Materials Science, 2013, 19(4): 461-464.
[54] ACKERMANN S, SCHEFFE J R, DUSS J, et al.Morphological Characterization and Effective Thermal Conductivity of Dual-Scale Reticulated Porous Structures[J]. Materials, 2014, 7(11): 7173-7195.
[55] ZHANG M J, HE M L, GU H Z, et al.Influence of Pore Distribution on the Equivalent Thermal Conductivity of Low Porosity Ceramic Closed-Cell Foams[J]. Ceramics International, 2018, 44(16): 19319-19329.
[56] MORA-MONTEROS J, SUTER C, HAUSSENER S.Effective Conductivity of Porous Ceramics in a Radiative Environment[J]. Ceramics International, 2020, 46(3): 2805-2815.
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